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Downsizing in combination with turbocharging currently represents the main technology trend for meeting CO2 emissions with gasoline engines. Besides the well-known advantages of downsizing the compression ratio has to be reduced in order to mitigate knock at higher engine loads along with increased turbocharging demand to compensate for the reduction in power. Another disadvantage occurs at part load with increasing boost pressure levels causing the part load efficiencies to deteriorate. The application of a variable compression ratio (VCR) system can help to mitigate these disadvantages. The 2-stage VCR system with variable kinetic lengths entails variable powertrain components which can be used instead of the conventional components and thus only require minor modifications for existing engine architectures. The presented variable length connecting rod system has been continuously developed over the past years.

The interest in electric propulsion of vehicles has increased in recent years and is being discussed extensively by experts as well as the public. Up to now the driving range and the utilization of pure electric vehicles are still limited in comparison to conventional vehicles due to the limited capacity and the long charging times of today's batteries. This is a challenge to customer acceptance of a pure electric vehicle, even for a city car application. A Range Extender concept could achieve the desired customer acceptance, but should not impact the “electric driving” experience, and should not cause further significant increases in the manufacturing and purchasing cost. The V2 engine concept presented in this paper is particularly suited to a low cost, modular vehicle concept. Advantages regarding packaging can be realized with the use of two generators in combination with the V2 engine.

The problem with traditional drive cycle fuel economy analysis is that kinematic (backward looking) models do not account for transient differences in charge air handling systems. Therefore, dynamic (forward looking) 1D performance simulation models were created to predict drive cycle fuel economy which encompass all the transient elements of fully detailed engine and vehicle models. The transient-capable technology of primary interest was mechanical supercharging which has the benefit of improved boost response and "time to torque." The benefits of a supercharger clutch have also been evaluated. The current US class 6-8 commercial vehicle market exclusively uses turbocharged diesel engines. Three vehicles and baseline powertrains were selected based on a high-level review of vehicle sales and the used truck marketplace. Fuel economy over drive cycles was the principal output of the simulation work. All powertrains are based on EPA 2010 emission regulations.

Real-world operation of diesel oxidation catalysts (DOCs), used in a variety of aftertreatment systems, subjects these catalysts to a large number of permanent and temporary deactivation mechanisms. These include thermal damage, induced by generating exotherm on the catalyst; exposure to various inorganic species contained in engine fluids; and the effects of soot and hydrocarbons, which can mask the catalyst in certain operating modes. While some of these deactivation mechanisms can be accurately simulated in the lab, others are specific to particular engine operation regimes. In this work, a set of DOCs, removed from prolonged service in the field, has been subjected to a detailed laboratory study. Samples obtained from various locations in these catalysts were used to characterize the extent and distribution of deactivation.

In this work, an alternative method is proposed and validated for quantifying the axial performance of a state-of-the-art Cu zeolite SCR catalyst. Catalyst cores of a standard length, with varying lengths of wash-coated regions were used to axially resolve the functional performance of the SCR catalyst. This proposed method was validated by quantifying the catalyst entrance and exit effects, as well as the effect of non-uniform wash-coat loading densities. This method is less susceptible to some of the complications highlighted in the previous studies, such as flow uniformity between channels, as well as radiative heating effects, since the product gases are sampled across the entire monolith cross-section rather than through a single catalyst channel. The specific catalyst functions quantified include: NO and NH₃ oxidation, NH₃ storage capacity, as well as NOx conversion efficiency.

Over the past few years, both global warming and rising oil prices led to a significantly increased demand for low fuel consumption in passenger cars. However, the necessity to also meet the limits of today's and future emission regulations makes it more and more difficult to maintain a high engine efficiency without the use of an expensive external exhaust gas after-treatment system. Therefore, new technologies that simultaneously prevent emission formation and reduce fuel consumption inside the internal combustion engine during the combustion process itself are of highest interest. This paper analyzes the influence of a catalytic coating of the combustion chamber on combustion, emission formation and fuel consumption. For this purpose, test runs with a production 2.0-liter, 4-cylinder, 4-valve, double overhead camshaft (DOHC), port fuel injection (PFI) gasoline engine were performed.

In recent years, ammonia slip catalysts (ASC) are being used downstream of an SCR system to minimize the ammonia slip. The dual-layer ASC is more attractive for its bi-functionality in reducing the ammonia and NOX emissions. It consists of two layers with the upper layer comprising a component with SCR functionality and the lower layer a PGM containing catalyst with oxidation functionality. Thus, both oxidation and SCR reactions take place in two different layers and are interlinked by the inter-layer mass transfer mechanism. In addition, adsorption and desorption kinetics between the gas and solid phases play a significant role. Mathematically, the overall system is a complex system of mass, momentum and energy transfer equations with temporal and spatial variables in both axial and radial directions. In this work, we focus on devising a suitable, computationally inexpensive model for such ASCs to be efficiently used for design, control and system optimization studies.

The effects of propylene (C₃H₆) and dodecane (n-C₁₂H₂₆) exposure on the NH₃-based selective catalytic reduction (SCR) performance of two Cu-exchanged zeolite catalysts were investigated. The first sample was a model Cu/beta zeolite sample and the second a state-of-the-art Cu/zeolite sample, with the zeolite material characterized by relatively small pores. Overall, the state-of-the-art sample performed better than the model sample, in terms of hydrocarbon inhibition (which was reduced) and N₂O formation (less formed). The state-of-the-art sample was completely unaffected by dodecane at temperatures lower than 300°C, and only slightly inhibited (less than 5% conversion loss), for standard SCR, by C₃H₆. There was no evidence of coke formation on this catalyst with C₃H₆ exposure. The model sample was more significantly affected by hydrocarbon exposure. With C₃H₆, inhibition is associated with its partial oxidation intermediates adsorbed on the catalyst surface.

Stringent global emissions legislation demands effective NOx reduction strategies, particularly for the aftertreatment, and current typical liquid urea SCR systems achieve efficiencies greater than 90% [1]. However, with such high-performing systems comes the trade-off of requiring a tank of reductant (urea water solution) to be filled regularly, usually as soon as the fuel fillings or as far as oil changes. Advantages of solid reductants, particularly ammonium carbamate, include greater ammonia densities, enabling the reductant refill interval to be extended several multiples versus a given reductant volume of urea, or diesel exhaust fluid (DEF) [2]. An additional advantage is direct gaseous ammonia dosing, enabling reductant injection at lower exhaust temperatures to widen its operational coverage achieving greater emissions reduction potential [3], as well as eliminating deposits, reducing mixing lengths, and avoiding freeze/thaw risks and investments.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. Typical 2010 Heavy-Duty systems include a DOC along with a catalyzed soot filter (CSF) in addition to the SCR sub-assembly. There is a strong desire to further increase the NOx conversion capability of such systems, to enable additional fuel economy savings by allowing engines to be calibrated to higher engine-out NOx levels. One potential approach is to replace the CSF with a diesel particulate filter coated with SCR catalysts (SCR-DPF) while keeping the flow-through SCR elements downstream, which essentially increases the SCR volume in the after-treatment assembly without affecting the overall packaging. In this work, a system consisting of SCR-DPF was evaluated in comparison to the DOC + CSF components from a commercial 2010 DOC + CSF + SCR system on an engine with the engine EGR on (standard engine-out NOx) and off (high engine-out NOx).

Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.

Tier 4 emissions legislation is emerging as a clear pre-cursor for widespread adoption of exhaust aftertreatment in off-highway applications. Large bore engine manufacturers are faced with the significant challenge of packaging a multitude of catalyst technologies in essentially the same design envelope as their pre-Tier 4 manifestations, while contending with the fuel consumption consequences of the increased back pressure, as well as the incremental cost and weight associated with the aftertreatment equipment. This paper discusses the use of robust metallic catalysts upstream of the exhaust gas turbine, as an effective means to reduce catalyst volume and hence the weight and cost of the entire aftertreatment package. The primarily steady-state operation of many large bore engine applications reduces the complication of overcoming pre-turbine catalyst thermal inertia under transient operation.

Beginning in 2010, implementation of on-board diagnostics (OBD) is mandatory for all the heavy-duty engine applications in the United States. The task of developing OBD strategies and calibrating them is a challenging one. The process involves a strong interdependency on base engine emissions, controls and regulations. On top of that the strategies developed as a result of the regulatory requirements need to go through a stringent and time-intensive process of software implementation and integration. The recent increasing demands to minimize the development process have been pushing the envelope on the methodologies used in developing the strategies and the calibration for robust monitoring. The goal of this paper is to provide a concise overview of a process utilized to help the development, testing and calibration of the OBD strategies on a 2010 model year heavy-duty diesel engine.

Oxidation of NO to NO₂ over a Diesel Oxidation Catalyst (DOC) plays an important role in different types of aftertreatment systems, by enhancing NOx storage on adsorber catalysts, improving the NOx reduction efficiency of SCR catalysts, and enabling the passive regeneration of Diesel Particulate Filters (DPF). The presence of hydrocarbon (HC) species in the exhaust is known to affect the NO oxidation performance over a DOC; however, specific details of this effect, including its underlying mechanism, remain poorly understood. Two major pathways are commonly considered to be responsible for the overall effect: NO oxidation inhibition, due to the presence of HC, and the consumption of the NO₂ produced by reaction with hydrocarbons. In this work we have attempted to decouple these two pathways, by adjusting the catalyst inlet concentrations of NO and NO₂ to the thermodynamic equilibrium levels and measuring the composition changes over the catalyst in the presence of HC species.

Since early 2010, most new medium- and heavy-duty diesel vehicles in the US rely on urea-based Selective Catalytic Reduction (SCR) technology for meeting the most stringent regulations on nitrogen oxides (NOx) emissions in the world today. Catalyst technologies of choice include Copper (Cu)- and Iron (Fe)-based SCR. In this work, the performances of Fe-SCR and Cu-SCR were investigated in the most commonly used DOC + CSF + SCR system configuration. Cu-SCR offered advantages over Fe-SCR in terms of low temperature conversion, NO₂:NOx ratio tolerance and NH₃ slip, while Fe-SCR demonstrated superior performance under optimized NO₂:NOx ratio and at higher temperatures. The Cu-SCR catalyst displayed less tolerance to sulfur (S) exposure. Reactor testing has shown that Cu-SCR catalysts deactivate at low temperature when poisoned by sulfur.

The low-temperature performance characteristics of a commercial lean NOX trap catalyst were evaluated using infra-red thermography (IRT) before and after a high-temperature aging step. Reaction tests included propylene oxidation, oxygen storage capacity measurements, and simulated cycling conditions for NOX reduction, using H₂ as the reductant during the regeneration step of the cycle. Testing with and without NO in the lean phase showed thermal differences between the reductant used in reducing the stored oxygen and that for nitrate decomposition and reduction. IRT clearly demonstrated where NOX trapping and regeneration were occurring spatially as a function of regeneration conditions, with variables including hydrogen content of the regeneration phase and lean- and rich-phase cycle times.

Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

Effects of six different fuels on low temperature premixed compression ignition (PCI) combustion were experimentally investigated in this paper with a light-duty HSDI engine. The PCI combustion concept reduces NOx and smoke emissions simultaneously by low temperature and premixed combustion, respectively. To achieve low temperature and premixed combustion, the ignition delay is prolonged and the injection duration is shortened. Six fuels were chosen to examine the influence of cetane number (CN) and other fuel properties on low temperature PCI combustion. The fuel selection also included a pure Gas- to-Liquid (GTL) fuel and a blend of base diesel and 20% soy based biodiesel (B20). Fuel effects were studied over a matrix of seven part load points in the low temperature combustion mode. The seven part load points were specified by engine speed (RPM) and brake mean effective pressure (BMEP).

Emission control systems combining NOx Adsorber catalysts with Selective Catalytic Reduction catalysts (NAC + SCR) offer potential performance advantages for NOx control under lean conditions compared to systems consisting of only one of these technologies. The combined systems, however, also present new catalyst design challenges. In contrast to NAC-only systems, formation of NH₃ over the NAC component under NOx regeneration conditions is a desirable feature in the combined (NAC + SCR) system. The SCR component in the combined system needs to be as thermally durable as the stand-alone SCR technology and also has to withstand repeated high-temperature lean/rich transients encountered during periodic desulfation of the upstream NAC component. In this study, advanced NAC and SCR components were developed specifically for the combination system. The advanced NAC component exhibited a wider operating temperature window and higher NH₃ generation activity at reduced PGM loading.

Raising interest in Diesel powered passenger cars in the United States in combination with the government mandated policy to reduce dependency of foreign oil, leads to the desire of operating Diesel vehicles with Biodiesel fuel blends. There is only limited information related to the impact of Biodiesel fuels on the performance of advanced emission control systems. In this project the implementation of a NOx storage and a SCR emission control system and the development for optimal performance are evaluated. The main focus remains on the discussion of the differences between the fuels which is done for the development as well as useful life aged components. From emission control standpoint only marginal effects could be observed as a result of the Biodiesel operation. The NOx storage catalyst results showed lower tailpipe emissions which were attributed to the lower exhaust temperature profile during the test cycle. The SCR catalyst tailpipe results were fuel neutral.